Can acyclic conformational control be achieved via a sulfur–fluorine gauche effect?
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چکیده
منابع مشابه
Can acyclic conformational control be achieved via a sulfur-fluorine gauche effect?
The gauche conformation of the 1,2-difluoroethane motif is known to involve stabilising hyperconjugative interactions between donor (bonding, σC-H) and acceptor (antibonding, σ*C-F) orbitals. This model rationalises the generic conformational preference of F-Cβ-Cα-X systems (φFCCX ≈ 60°), where X is an electron deficient substituent containing a Period 2 atom. Little is known about the correspo...
متن کاملCan acyclic conformational control be achieved via a sulfur–fluorine gauche effect?† †Electronic supplementary information (ESI) available. CCDC 1048074–1048078. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c5sc00871a
Organisch Chemisches Institut, and Excell Westfälische Wilhelms-Universität Münster E-mail: [email protected] Department of Chemistry and Biochemistry Charles E. Young Drive East, Los Angeles 90 edu Excellence Cluster EXC 1003, Cells in M Münster, Münster, Germany † Electronic supplementary information ( For ESI and crystallographic data in CI 10.1039/c5sc00871a ‡ X-ray crystallograp...
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ژورنال
عنوان ژورنال: Chemical Science
سال: 2015
ISSN: 2041-6520,2041-6539
DOI: 10.1039/c5sc00871a